It sounds like you should be able to.
Provided you share a folder on the host properly you should just be able to connect to it by using "\\PC IP address\sharename" typed into an explorer address bar.
You should be prompted for a username and password if you've opened the share to locally authenticated users rather than open to the world.
---------- Post added at 08:54 ---------- Previous post was at 08:53 ----------
Bear in mind however, firewalls installed on any of the machines involved could get in the way unless they're properly configured.

to CF by the way.