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-   -   The lights are on... (https://www.cableforum.uk/board/showthread.php?t=33690053)

Osem 05-10-2012 09:47

The lights are on...
 
... for now:

Quote:

Britain risks running out of energy generating capacity in the winter of 2015-16, according to the energy regulator Ofgem.
http://www.bbc.co.uk/news/business-19842401

But is anyone in government 'at home' when it comes to dealing with this problem? We've been hearing the warnings for years and they're still dithering so far as I can see.

Derek 05-10-2012 09:51

Re: The lights are on...
 
Quote:

Originally Posted by Osem (Post 35481596)
But is anyone in government 'at home' when it comes to dealing with this problem?

Well they are at one of their homes, probably burning the 'plebs' in a roaring open fire.

Damien 05-10-2012 09:58

Re: The lights are on...
 
It's because they keep kicking a decision down the can because, turns out, there is no miracle solution to it. Build the nuclear power stations and be done with it already.

Osem 05-10-2012 09:58

Re: The lights are on...
 
Possibly ;) But let's face it, the last lot were in for 13 years and seemed to do precious little about this problem and that's after having opened the immigration floodgates. The lack of foresight is quite bizarre and very worrying.

Chris 05-10-2012 10:04

Re: The lights are on...
 
We need lots of great big nuclear power stations as soon as possible. We then need to convert Blackpool Tower into a drilling rig so we can get at all the shale gas. Meanwhile, anyone with any spare savings, put them in shares of whichever company makes the best petrol generators, because a lot of people are going to be buying them soon.

Damien 05-10-2012 10:18

Re: The lights are on...
 
Quote:

Originally Posted by Osem (Post 35481605)
Possibly ;) But let's face it, the last lot were in for 13 years and seemed to do precious little about this problem and that's after having opened the immigration floodgates. The lack of foresight is quite bizarre and very worrying.

It's because governments look at the problem and they don't like the answer - nuclear power. The rest aren't feasible, solar and wind is nowhere near efficient enough yet to be a serious contender whereas fossil fuels pollute more, are more expensive and depend on a finite resource. Labour should have done something in the 13 years they had, they didn't, so now it's the current governments responsibility and they're not doing it either.

Chris 05-10-2012 10:29

Re: The lights are on...
 
Adding shale gas to the energy mix in the US has caused a rapid and significant reduction in that country's carbon output, because it is far less polluting than the coal and oil it can immediately and directly replace. There is also enough of it to last a century.

This country's dash for wind power is a busted flush now the public has woken up to the sheer number of turbines that would be required to make a dent in our energy requirements. Once upon a time I would have argued that they were an interesting addition to the landscape but the problem now is they're absolutely everywhere, we've still barely begun, and they still cost an absolute fortune which we're all paying for in artificially inflated energy bills.

Jimmy-J 05-10-2012 10:53

Re: The lights are on...
 
We need plenty of these---> Free Energy Generator :D

Taf 05-10-2012 12:09

Re: The lights are on...
 
Treadmill generators in every city, town and village.

The unemployed forced to walk in them for long shifts day and night.

Maggy 05-10-2012 12:22

Re: The lights are on...
 
Or we could find ways to use fuel more efficiently and stop wasting it.

---------- Post added at 13:22 ---------- Previous post was at 13:15 ----------

And to add injury..

http://www.bbc.co.uk/news/business-19830232

Quote:

Electric cars might pollute much more than petrol or diesel-powered cars, according to new research.
The Norwegian University of Science and Technology study found greenhouse gas emissions rose dramatically if coal was used to produce the electricity.
Electric car factories also emitted more toxic waste than conventional car factories, their report in the Journal of Industrial Energy said.

Ken W 05-10-2012 12:44

Re: The lights are on...
 
[QUOTE=Maggy J;35481667]Or we could find ways to use fuel more efficiently and stop wasting it.

---------- Post added at 13:22 ---------- Previous post was at 13:15 ----------

Switch off rather than leave TV, set top box excreta on standby.
For example the Virgin Media TIVO consumes 20 watts in standby with no recordings set.

Multiply that by the number of units that are left on standby.

AdamD 05-10-2012 14:14

Re: The lights are on...
 
As much as I love the futuristic visions of a squeaky clean, renewable energy powered country, it simply isn't viable right now

I mean how many solar panels/turbines etc have been put up in the last 10 years, yet, we're still running out of spare capacity?

The only way forward for the time being, is nuclear.

Sirius 05-10-2012 14:31

Re: The lights are on...
 
Quote:

Originally Posted by Chris (Post 35481609)
We need lots of great big nuclear power stations as soon as possible. We then need to convert Blackpool Tower into a drilling rig so we can get at all the shale gas. Meanwhile, anyone with any spare savings, put them in shares of whichever company makes the best petrol generators, because a lot of people are going to be buying them soon.

The nimby's will put a stop to any expansion :mad:

Chris 05-10-2012 14:44

Re: The lights are on...
 
Quote:

Originally Posted by Maggy J (Post 35481667)
Or we could find ways to use fuel more efficiently and stop wasting it.

We all have our part to play, however domestic CO2 production is less than 15% of the UK total and on current estimates, British homes are only going to manage to reduce their CO2 output by about 10%, or 1.5% of the total national emissions, by 2020. Domestic energy efficiency measures really are just spitting on an inferno.

The fact is, economic growth consumes energy. If the economy grows, then our energy consumption grows. The loudest voices demanding radical energy efficiency measures are luddite greens who would actually quite like our economy to collapse backwards into what they delusionally believe to be some sort of quasi-agrarian utopia.

If we need to reduce our CO2 emissions (and IMO it is an if), then the way to do that is by employing power generation methods that produce less CO2, not by futile attempts at using less energy.

Jimmy-J 05-10-2012 14:49

Re: The lights are on...
 
Quote:

Originally Posted by Sirius (Post 35481735)
The nimby's will put a stop to any explosion :mad:

I fixed that for you. ;)

dilli-theclaw 05-10-2012 14:51

Re: The lights are on...
 
We are go g to use nmbys as control rods?

Ken W 05-10-2012 14:52

Re: The lights are on...
 
Quote:

Originally Posted by AdamD (Post 35481727)
As much as I love the futuristic visions of a squeaky clean, renewable energy powered country, it simply isn't viable right now

I mean how many solar panels/turbines etc have been put up in the last 10 years, yet, we're still running out of spare capacity?

The only way forward for the time being, is nuclear.

Didcot power station will be shut down next year.

Sparkle 05-10-2012 14:54

Re: The lights are on...
 
To be fair though, does anyone want one of those in their back yard? I live near a wind farm, and though a bit unsightly - I've gotten used to seeing them every time I look out the window. But a nuke station? No thanks.

---------- Post added at 15:54 ---------- Previous post was at 15:53 ----------

Quote:

Originally Posted by Ken W (Post 35481749)
Didcot power station will be shut down next year.

Didcot power station is coal/gas fired though.

Chris 05-10-2012 14:54

Re: The lights are on...
 
Quote:

Originally Posted by Sparkle (Post 35481751)
To be fair though, does anyone want one of those in their back yard? I live near a wind farm, and though a bit unsightly - I've gotten used to seeing them every time I look out the window. But a nuke station? No thanks.

It's generally possible to build a new reactor next door to an existing one. And the communities that already live with them tend to appreciate them because they bring a shed load of cash into the local economy.

Sparkle 05-10-2012 15:02

Re: The lights are on...
 
Quote:

Originally Posted by Chris (Post 35481753)
It's generally possible to build a new reactor next door to an existing one. And the communities that already live with them tend to appreciate them because they bring a shed load of cash into the local economy.

I can understand business owners being happy with the extra business, and perhaps those who moved locally after the powerplant was built (as they knew what they there were moving next to), but I'd hate to think the reaction if a random community where chosen and a nuclear facility constructed. I'd imagine the local community would go bananas.

Chris 05-10-2012 15:11

Re: The lights are on...
 
Quite possibly, however IIRC all the proposed sites for new nukes in the UK are next to existing or decommissioned ones anyway, so it's a little moot.

Interestingly, here in Scotland the SNP has ruled out new nuclear power stations because it thinks we can get all our electricity from wind plus base-load from so-called 'clean coal'. However the plans to build a clean coal plant at Hunterston (which, fortuitously, has both a coal import facility and two existing nuclear power stations, so easy connection to the Grid) fell apart at the seams* because clean coal is a myth. Nobody has yet demonstrated that carbon capture can work on a commercial scale.

So, at present, without even a theoretical acceptance that nuclear power will be required to be built in Scotland, the chances are that our energy crisis could be rather worse than the one down south. It might be alleviated slightly by nuclear power coming across the border on the interconnector, of course, but my understanding is that the Grids in Scotland and England are essentially separate so I'm not certain of how much of a power shortage due to insufficient generation within Scotland can be made up by English electricity.

*boom, boom.

martyh 05-10-2012 15:12

Re: The lights are on...
 
Problem is that the government has announced that we need loads more homes to satisfy demand and yet they fail to realise that all those homes will need power ,it's ok building 100,000 new houses but where's the extra electricity,gas and water going to come from to feed the new homes,not to mention the new shops and business premises that will need services

RizzyKing 05-10-2012 18:58

Re: The lights are on...
 
A small step would be to make it mandatory that all new builds have solar panels aand where possible all older buildings that can have them get them. It is not a solution but if energy is goinng to get as close to the knuckle as it seems it might just make that tiny difference. I get the feeling though it will take something major to kick start any government into actually dealing with the energy situation in this country none of them want to deal with it but they all love talking about it as though they have the aanswer.

Maggy 05-10-2012 19:57

Re: The lights are on...
 
Trouble is each government starts off think we have only 5 years.Then if they get re-elected then they can't believe their luck but still can't think more than 5 years ahead.Then if they get re-elected it's probably with a small majority and anything long term that they might have overseen 10 years before can't be implemented because of opposition.

RizzyKing 06-10-2012 15:16

Re: The lights are on...
 
Yeah i think thats the problem with professional politicians they are all too worried about short term objectives they seem incapable of making the decisions regarding long terrm problems and the problem will only get worse before it gets better. Sadly there is so much oneupmanship in politics that any chaance of independent bodies tasked with dealing with these long term issues is highly unlikely.

martyh 07-10-2012 07:02

Re: The lights are on...
 
maybe this is the answer ,i think it's a good idea

Quote:

Cars, homes and factories could be powered using the air we breathe in the future, according to engineers at a special summit.
British scientists developing the technology say normal air can be used to store energy by cooling it to 190C, turning it into a liquid.
http://news.sky.com/story/991949/liq...-of-the-future

slowcoach 08-10-2012 02:10

Re: The lights are on...
 
There is no alternative to fossil fuels at the moment. To go all nuclear would currently require 10,000 of the biggest generators to be built and then we would run out of known Uranium deposits in 20 – 25 years, so nuclear can only be considered a stop gap at best, remember this is not just a UK problem.

Chris 08-10-2012 08:16

Re: The lights are on...
 
The long-term future of nuclear power lies in thorium, rather than uranium, and there's more than enough thorium about. India has been going hell-for-leather on thorium reactor development and plans to have dozens of them operating in a little over a decade. They claim to be close to having the first one running now.

Damien 08-10-2012 08:32

Re: The lights are on...
 
Everything in this country is too slow. We're never going to get anything done.

Osem 08-10-2012 09:03

Re: The lights are on...
 
It appears that liquid air 'storage' could help the situation a little but it's still clear to me that we need long term solutions to this problem, especially if we're going to see the sort of population growth that's being predicted and the likelihood that migration is going to remain an issue.

http://www.bbc.co.uk/news/science-environment-19785689

Quote:

Turning air into liquid may offer a solution to one of the great challenges in engineering - how to store energy.

The Institution of Mechanical Engineers says liquid air can compete with batteries and hydrogen to store excess energy generated from renewables.

Chris 08-10-2012 09:10

Re: The lights are on...
 
Quote:

Originally Posted by Osem (Post 35482735)
It appears that liquid air 'storage' could help the situation a little but it's still clear to me that we need long term solutions to this problem, especially if we're going to see the sort of population growth that's being predicted and the likelihood that migration is going to remain an issue.

http://www.bbc.co.uk/news/science-environment-19785689

Yes, I saw that the other day. I'm still trying to decide if the article is demonstrating journalistic ignorance on a massive scale or whether I'm missing something fundamental, because it seems to me that if you super-cool air down to a liquid you're removing the energy from it, rather than storing any energy in it. What you're actually doing, I believe, is creating a source of potential energy, because of the useful work that can be done when the liquid air is allowed to recirculate with other components at 'room temperature'. The actual energy in that system comes from the environment, rather than the liquid air, but it is the liquid air that allows the energy to be extracted.

Any scientists about to enlighten us further?

Damien 08-10-2012 09:13

Re: The lights are on...
 
These are all theoretical though. The problem is pressing and even if we do, as we should, manage to reduce individual consumption we'll still see increasing demand. It will take at least 10 years to get a new nuclear power plant built and we're discussing a storage of electricity in just 3 years. Successive Governments have acted grossly irresponsibly in their continued failure to address the issue in favour of kicking it down the road in the hope that a cheap, clean and efficient renewable power source will appear.

Osem 08-10-2012 10:16

Re: The lights are on...
 
It's a bit more than theoretical - it's been successfully trialled over the last 2 years and the technology is relatively simple it seems. Of course this can't solve our problems but it might just buy us a little more time in which to do so. That's presuming our glorious leaders don't simply waste that time and continue dodging the tough decisions. Given projected demand v. output and what we've seen happen to oil/gas prices, I really don't understand why this matter isn't being treated as a matter of extreme national importance. :confused:

Chris 08-10-2012 11:17

Re: The lights are on...
 
Because nobody wants to be the one to stand up and admit that the CO2 reduction targets foisted on us by Europe are insane. Being un-green is very un-cool at the moment, despite the fact that in the real world economy it simply doesn't add up.

This country needs nuclear and shale gas power in abundance. Both are achievable, neither are politically very palatable. Sadly I suspect nobody will act on this until there is a clear electoral advantage, and because the green dogma is currently in the ascendency there won't be an electoral advantage in building traditional power stations until the lights start going out according to a rota, as per the 1970s.

Damien 08-10-2012 11:35

Re: The lights are on...
 
Quote:

Originally Posted by Chris (Post 35482769)
Because nobody wants to be the one to stand up and admit that the CO2 reduction targets foisted on us by Europe are insane. Being un-green is very un-cool at the moment, despite the fact that in the real world economy it simply doesn't add up.

This country needs nuclear and shale gas power in abundance. Both are achievable, neither are politically very palatable. Sadly I suspect nobody will act on this until there is a clear electoral advantage, and because the green dogma is currently in the ascendency there won't be an electoral advantage in building traditional power stations until the lights start going out according to a rota, as per the 1970s.

Osborne has just announced 'investment' in shale gas.

martyh 08-10-2012 16:35

Re: The lights are on...
 
Quote:

Originally Posted by Chris (Post 35482739)
Yes, I saw that the other day. I'm still trying to decide if the article is demonstrating journalistic ignorance on a massive scale or whether I'm missing something fundamental, because it seems to me that if you super-cool air down to a liquid you're removing the energy from it, rather than storing any energy in it. What you're actually doing, I believe, is creating a source of potential energy, because of the useful work that can be done when the liquid air is allowed to recirculate with other components at 'room temperature'. The actual energy in that system comes from the environment, rather than the liquid air, but it is the liquid air that allows the energy to be extracted.

Any scientists about to enlighten us further?

As i understand it,it gets cooled to -190C which is an unnatural state and as soon as the air starts to expand it takes up more room so will be capable of pushing a piston or turning a turbine ,pretty much the same principle as the internal combustion engine where a spark explodes petrol into a gaseous state to force the piston down .The biggest problem is keeping the air liquid for long periods in a car ,an idea probably more suited to power stations where it is already in use on a trial basis

Sparkle 09-10-2012 18:44

Re: The lights are on...
 
Quote:

Originally Posted by Chris (Post 35482739)
Yes, I saw that the other day. I'm still trying to decide if the article is demonstrating journalistic ignorance on a massive scale or whether I'm missing something fundamental, because it seems to me that if you super-cool air down to a liquid you're removing the energy from it, rather than storing any energy in it. What you're actually doing, I believe, is creating a source of potential energy, because of the useful work that can be done when the liquid air is allowed to recirculate with other components at 'room temperature'. The actual energy in that system comes from the environment, rather than the liquid air, but it is the liquid air that allows the energy to be extracted.

Any scientists about to enlighten us further?

Well, as I do this stuff in my line of work I suppose I can contribute something here. I use calculators occasionally for calculating carot and open rankine efficiencies so I can understand that the engineers where saying, though I really don't think the journalist who wrote the SKY article has any idea what they are talking about.
http://news.sky.com/story/991949/liq...-of-the-future

The SKY news article really made me cringe, as it is not the fuel of the future at all, clearly this is just an energy storage method. A temporary one at that. The comments to the article were even worse, and when peeps started saying you can "store liquid air" at room temperature, I had to comment in the comments section. No such thing as liquefied air at room temperature, it must be maintained below critical temperature at cryogenic temperatures.

Anyway, energy is indeed being stored by the liquefied air. A great deal of energy in fact. The reason it's easier to store energy as liquid air is rather complicated and drawn out. It could be instead stored as heat absorbed within some other medium (say a material with a high heat capacity) and used to expand air to drive a piston, but there are limitations to that as I'll try and illustrate.

Thermodynamically speaking, work is required to remove the heat from the air to cool in the first place (like compressing a spring) and then the liquefied air stored in a thermally insulated vessel (such as a nitrogen dewar).
Although the temperature of the cooled air had of course cooled, the air temperature of the hot side of the carnot cycle had in fact increased. The cooled air possesses decreased entropy (the hot side of the refrigeration system has increased entropy) and of course by the second law of thermodynaics, entropy of a system will always try to increase when it can. Which it does when the liquefied air is heated.

This work (required from the refrigeration pump/stirling cryopump to cool the air) is easily calculated using long established engineering principles. However, when the liquid air is later heated (say by passing through a small heat exchanger), the thermodynamic energy that was used to create it in the first place (assuming 100% efficiency), is then released in the form of pressure through a process called isobaric expansion. Its just a release of stored potential energy.

Bear in mind of course, that the refrigeration system used to produce the liquid air in the first place, will not have been 100% efficient. There will be a small margin lost due to friction. So the energy recoverable from the liquefied air will not be quite as high as the energy consumed to produce it in the first place. Also, the pneumatic motor used to extract the energy, won't be 100% efficient either. Since the liquefied air system is proposed to store off peak energy (cheaper per kWh), its only viable so much as a profit is made (the balance between normal grid supply and off-peak liquid air storage being determined by the thermodynamic loss margin, mentioned above). Too high a loss means a reduced amount of air can be produced and still remain a profitable/viable option. Of course that's just common sense really.

As for the amount of energy that can be recovered from liquefied air, it really depends on how it is achieved.
In all likelihood it will be combination of isobaric and isothermal processes.
So to give an approximate indication, for calculation purposes its easier to simplify the process by assuming 1 litre liquid, undergoing isobaric expansion (constant pressure) to its critical point (max temp at which liquid an exist irrespective of pressure), and then confined and heated to its final temperature (298K, or 25 deg C) at constant volume, and then allowed to isothermally decompress whilst driving a piston.
Summing up the work done via isobaric decompression and isothermal decompression is a simple approach to estimating the amount of work that can be extracted.

Air is 78% nitrogen, so to simplify things lets assume the liquid air is liquid nitrogen (otherwise calculations will be duplicated for oxygen too, the extrapolate between to give the actual energy calculation for air, ignoring the 1% noble gases of course).
Density of liquid nitrogen is 807 kg/m3. Which is 807g per L.

All gas molecules at the same temperature occupy approximately the same volume due to kinetic motion. One mole (6.02 x 10^23 molecules) equals about 22.4 litres at STP (standard temperature and pressure, which is 0 deg C / 273.15 Kelvin and 1 atmosphere pressure).

Nitrogen is diatomic (N2) so one mole is 28 grams. So there are 28.8 (807/28) moles per litre of liquid nitrogen. Which at STP will occupy a volume of 645.6 litres (22.4 x 28.8).
The mechanical work done by expanding 1 litre of N2 at its boiling point to a final volume of 645.6 litres at STP is given by:

For isobaric process, expanding from 1L liquid nitrogen, to its critical temperature and pressure. This is 126.19 deg K, and 3.3978 x 10^6 Pa.
To calculate the volume at the critical point, use ideal gas law.
PV=nRT. Rearranging, V=(nRT)/P.
n=28.8 mol
R=8.3145 J/mol/K
T=126.19

Solving for V, volume is 0.008893 or 8.893 litres (volume at critical point).

Heat to 298K, then assume isothermal expansion to drive piston to do mechanical work.
isothermal expansion work is given by: w=nRT ln(final voume/initial volume)
Final volume is 28.8 mol N2 at 298 K, use ideal gas law. Gives 0.7044 m3.

w= 28.8 x 8.3145 x 298 x ln(final volume/initial volume).
w = 311985 J or 311.985 kJ per litre of liquid N2 or 386.6 kJ/Kg

Of course it won't be possible to extract all work as usable energy so the actual value will be somewhat less than this.

Here's a calculator that can be used to double check the sums.
http://hyperphysics.phy-astr.gsu.edu...rmo/isoth.html

So for 1 litre, *most* of 311 kJ should be extractable as usable work.
One horsepower is 746 Joules/sec. At 100% efficiency, 311 kJ will produce one horsepower for 418 seconds or about 7 minutes or 100 horsepower for 4.18 seconds.

The actual figure will depend on the pneumatic motor, which would be tested to yield a figure. Assume the efficiency is a reasonable 85%.

Whereas, if the energy were *instead* being stored in the form of heat rather than liquefied air, due to the low thermodynamic efficiency of expansion, in order to match 85% efficiency, thermodynamic efficiency is given by:
http://en.wikipedia.org/wiki/Thermodynamic_cycle

Ambient temperature will be assumed to be 25 deg C (298 deg K).
efficiency, n, given by: n = 1 - (Temp L / Temp H)
So to achieve 85% efficiency:

0.85 = 1 - (298 / hot temperature)
Hot temperature = 1986.67 deg K or 1713.52 deg C
Any temperature below 1713 deg C cannot be used to yield a thermodynamic efficiency of 85%, it will be lesser. So in practise, you would need a hot sink that is thousands of degrees and cannot be cooled below 1713 deg C without compromising efficiency.

Therefore, you can see its far easier to store liquid air, than to thermally insulate a heat source to thousands of degrees. Even then, it would only be with the limitation of only allowing the heat source too cool to 1713 deg C before sending it back to the furnace for reheating. Not to mention that materials cannot withstand these temp ranges and the heat could never be contained/insulated using current technology. Using this cryogenic process not only makes the technology simpler, but thermodynamically its more efficient because of the extremely high gas expansion ratio of expanding liquid nitrogen or air.

Anyway, I didn't intend for the wall of text but that is the simplest way I could think of to give a run down of the theory and calculation(s).

Sirius 09-10-2012 18:52

Re: The lights are on...
 
Quote:

Originally Posted by Sparkle (Post 35483245)
Well, as I do this stuff in my line of work I suppose I can contribute something here. I use calculators occasionally for calculating carot and open rankine efficiencies so I can understand that the engineers where saying, though I really don't think the journalists who wrote either the BBC or SKY article have any idea what they are talking about.
http://news.sky.com/story/991949/liq...-of-the-future

The SKY news article really made me cringe, as it is not the fuel of the future at all, clearly this is just an energy storage method. A temporary one at that. The comments to the article were even worse, and when peeps started saying you can "store liquid air" at room temperature, I had to comment in the comments section. No such thing as liquefied air at room temperature, it must be maintained below critical temperature at cryogenic temperatures.

Anyway, energy is indeed being stored by the liquefied air. A great deal of energy in fact. The reason it's easier to store energy as liquid air is rather complicated and drawn out. It could be instead stored as heat absorbed within some other medium (say a material with a high heat capacity) and used to expand air to drive a piston, but there are limitations to that as I'll try and illustrate.

Thermodynamically speaking, work is required to remove the heat from the air to cool in the first place (like compressing a spring) and then the liquefied air stored in a thermally insulated vessel (such as a nitrogen dewar).
Although the temperature of the cooled air had of course cooled, the air temperature of the hot side of the carnot cycle had in fact increased. The cooled air possesses decreased entropy (the hot side of the refrigeration system has increased entropy) and of course by the second law of thermodynaics, entropy of a system will always try to increase when it can. Which it does when the liquefied air is heated.

This work (required from the refrigeration pump/stirling cryopump to cool the air) is easily calculated using long established engineering principles. However, when the liquid air is later heated (say by passing through a small heat exchanger), the thermodynamic energy that was used to create it in the first place (assuming 100% efficiency), is then released in the form of pressure through a process called isobaric expansion. Its just a release of stored potential energy.

Bear in mind of course, that the refrigeration system used to produce the liquid air in the first place, will not have been 100% efficient. There will be a small margin lost due to friction. So the energy recoverable from the liquefied air will not be quite as high as the energy consumed to produce it in the first place. Also, the pneumatic motor used to extract the energy, won't be 100% efficient either. Since the liquefied air system is proposed to store off peak energy (cheaper per kWh), its only viable so much as a profit is made (the balance between normal grid supply and off-peak liquid air storage being determined by the thermodynamic loss margin, mentioned above). Too high a loss means a reduced amount of air can be produced and still remain a profitable/viable option. Of course that's just common sense really.

As for the amount of energy that can be recovered from liquefied air, it really depends on how it is achieved.
In all likelihood it will be combination of isobaric and isothermal processes.
So to give an approximate indication, for calculation purposes its easier to simplify the process by assuming 1 litre liquid, undergoing isobaric expansion (constant pressure) to its critical point (max temp at which liquid an exist irrespective of pressure), and then confined and heated to its final temperature (298K, or 25 deg C) at constant volume, and then allowed to isothermally decompress whilst driving a piston.
Summing up the work done via isobaric decompression and isothermal decompression is a simple approach to estimating the amount of work that can be extracted.

Air is 78% nitrogen, so to simplify things lets assume the liquid air is liquid nitrogen (otherwise calculations will be duplicated for oxygen too, the extrapolate between to give the actual energy calculation for air, ignoring the 1% noble gases of course).
Density of liquid nitrogen is 807 kg/m3. Which is 807g per L.

All gas molecules at the same temperature occupy approximately the same volume due to kinetic motion. One mole (6.02 x 10^23 molecules) equals about 22.4 litres at STP (standard temperature and pressure, which is 0 deg C / 273.15 Kelvin and 1 atmosphere pressure).

Nitrogen is diatomic (N2) so one mole is 28 grams. So there are 28.8 (807/28) moles per litre of liquid nitrogen. Which at STP will occupy a volume of 645.6 litres (22.4 x 28.8).
The mechanical work done by expanding 1 litre of N2 at its boiling point to a final volume of 645.6 litres at STP is given by:

For isobaric process, expanding from 1L liquid nitrogen, to its critical temperature and pressure. This is 126.19 deg K, and 3.3978 x 10^6 Pa.
To calculate the volume at the critical point, use ideal gas law.
PV=nRT. Rearranging, V=(nRT)/P.
n=28.8 mol
R=8.3145 J/mol/K
T=126.19

Solving for V, volume is 0.008893 or 8.893 litres (volume at critical point).

Heat to 298K, then assume isothermal expansion to drive piston to do mechanical work.
isothermal expansion work is given by: w=nRT ln(final voume/initial volume)
Final volume is 28.8 mol N2 at 298 K, use ideal gas law. Gives 0.7044 m3.

w= 28.8 x 8.3145 x 298 x ln(final volume/initial volume).
w = 311985 J or 311.985 kJ per litre of liquid N2 or 386.6 kJ/Kg

Of course it won't be possible to extract all work as usable energy so the actual value will be somewhat less than this.

Here's a calculator that can be used to double check the sums.
http://hyperphysics.phy-astr.gsu.edu...rmo/isoth.html

So for 1 litre, *most* of 311 kJ should be extractable as usable work.
One horsepower is 746 Joules/sec. At 100% efficiency, 311 kJ will produce one horsepower for 418 seconds or about 7 minutes or 100 horsepower for 4.18 seconds.

The actual figure will depend on the pneumatic motor, which would be tested to yield a figure. Assume the efficiency is a reasonable 85%.

Whereas, if the energy were *instead* being stored in the form of heat rather than liquefied air, due to the low thermodynamic efficiency of expansion, in order to match 85% efficiency, thermodynamic efficiency is given by:
http://en.wikipedia.org/wiki/Thermodynamic_cycle

Ambient temperature will be assumed to be 25 deg C (298 deg K).
efficiency, n, given by: n = 1 - (Temp L / Temp H)
So to achieve 85% efficiency:

0.85 = 1 - (298 / hot temperature)
Hot temperature = 1986.67 deg K or 1713.52 deg C
Any temperature below 1713 deg C cannot be used to yield a thermodynamic efficiency of 85%, it will be lesser. So in practise, you would need a hot sink that is thousands of degrees and cannot be cooled below 1713 deg C without compromising efficiency.

Therefore, you can see its far easier to store liquid air, than to thermally insulate a heat source to thousands of degrees. Even then, it would only be with the limitation of only allowing the heat source too cool to 1713 deg C before sending it back to the furnace for reheating. Not to mention that materials cannot withstand these temp ranges and the heat could never be contained/insulated using current technology. Using this cryogenic process not only makes the technology simpler, but thermodynamically its more efficient because of the extremely high gas expansion ratio of expanding liquid nitrogen or air.

Anyway, I didn't intend for the wall of text but that is the simplest way I could think of to give a run down of the theory and calculation(s).

What can i say other than WOW :tu:

Chris 09-10-2012 18:56

Re: The lights are on...
 
Quote:

Originally Posted by Sparkle (Post 35483245)
the thermodynamic energy that was used to create it in the first place (assuming 100% efficiency), is then released in the form of pressure through a process called isobaric expansion. Its just a release of stored potential energy.

Major snippage of your highly informative post .... this little chunk here is what I was thinking the whole thing might be about, but it just seemed counter-intuitive to store energy in a system by removing heat (an easily understood form of energy) from it.

:spin:

Osem 02-05-2013 07:48

Re: The lights are on...
 
Quote:

Investment totalling a trillion Euros is required before the end of this decade if the European Union is to stave off an energy crisis.

That is the conclusion of an eight-month inquiry by the House of Lords into the EU power sector.

The Lords report says that a muddled Brussels energy policy is putting off big investors.

In addition, it says there needs to be greater support for Europe's emissions trading system (ETS).
http://www.bbc.co.uk/news/science-environment-22372088

Maybe there'll be less enquiries/reports and more action when the lights start going out....

Chris 02-05-2013 08:07

Re: The lights are on...
 
Greater support for the emissions trading system? How about a great big wooden stake through the heart of the emissions trading system. That's what it needs.

No more useless windmills - we need nukes and we need gas. And we need them quickly. Oh, and until they're on stream, there should be a law against closing down any more coal-fired stations. If the EU asks why, we can tell them it's none of their fecking business.

Osem 02-05-2013 08:49

Re: The lights are on...
 
I'm beginning to think there's something other than pure stupidity and short-termism going on here. Are we being deliberately steered towards a 'crisis' which will then require our glorious leaders to enforce draconian measures through which they might also be able to achieve those political ambitions they haven't otherwise been able to secure?

It's probably a sign of age related cynicism but the more I look around, the more I see evidence of a perfect storm on the horizon - one which will have dramatic effects on our entire way of life. Maybe I just had a bad night though... :)

Damien 02-05-2013 08:59

Re: The lights are on...
 
Quote:

Originally Posted by Osem (Post 35567412)
I'm beginning to think there's something other than pure stupidity and short-termism going on here. Are we being deliberately steered towards a 'crisis' which will then require our glorious leaders to enforce draconian measures through which they might also be able to achieve those political ambitions they haven't otherwise been able to secure?

No, probably that they don't want to commit political capital and money to an issue that wouldn't arise in their term. They won't get the credit or the blame. Politicians think about themselves and their position, not as part of a grander scheme.

slowcoach 02-05-2013 09:26

Re: The lights are on...
 
The current way of life is not sustainable, the current world population is not sustainable.
Under the New World Order there will be plenty to go around, for those that are connected to the grid.
As slaves, the rest of us will have more pressing things on our mind. ;)

Maggy 02-05-2013 09:39

Re: The lights are on...
 
Quote:

Originally Posted by Chris (Post 35567400)
Greater support for the emissions trading system? How about a great big wooden stake through the heart of the emissions trading system. That's what it needs.

No more useless windmills - we need nukes and we need gas. And we need them quickly. Oh, and until they're on stream, there should be a law against closing down any more coal-fired stations. If the EU asks why, we can tell them it's none of their fecking business.

:tu:

Osem 02-05-2013 09:45

Re: The lights are on...
 
Quote:

Originally Posted by Damien (Post 35567416)
No, probably that they don't want to commit political capital and money to an issue that wouldn't arise in their term. They won't get the credit or the blame. Politicians think about themselves and their position, not as part of a grander scheme.

I'm not sure the single state obsessed Eurocrats fit that category but that's another issue. ;)

There's no doubt there's been a large degree of plain dithering over recent decades but things in the world have changed dramatically in the last few years and I believe the 'rules of the game' are being slowly rewritten behind closed doors because a sesimic change in our way of life is on the cards and those with the power want to hold onto it. Who'd have predicted, even 10 years ago, what's been happening in China, India etc. and all the problems in Europe and the US? It'll all be done in 'our' best interests of course...

Does Amazon sell tin foil hats BTW?

Osem 13-10-2013 13:26

Re: The lights are on...
 
Quote:

Britain's energy sector is close to securing tens of billions of pounds in investment from the Far East, Energy Secretary Ed Davey has said.

He said a "massive" wave of investment in nuclear and other technology from China, Japan and Korea would help secure the UK's future power supply.
http://www.bbc.co.uk/news/uk-politics-24511829

Let's hope he's right and things start happening soon... :erm:

Sirius 13-10-2013 13:27

Re: The lights are on...
 
Quote:

Originally Posted by Osem (Post 35631551)
http://www.bbc.co.uk/news/uk-politics-24511829

Let's hope he's right and things start happening soon... :erm:

Omg you can bet the tree hugging greens will hate this with a vengeance

papa smurf 13-10-2013 13:47

Re: The lights are on...
 
Quote:

Originally Posted by Chris (Post 35481753)
It's generally possible to build a new reactor next door to an existing one. And the communities that already live with them tend to appreciate them because they bring a shed load of cash into the local economy.

and the local cats love em cos the fish have 3 heads ;)

Taf 13-10-2013 16:01

Re: The lights are on...
 
Foreign investment means foreign control.

Not that we control much in the UK anymore.

martyh 13-10-2013 17:44

Re: The lights are on...
 
The way things move in this country it'll still be 20-30yrs before we see anything

Sirius 13-10-2013 18:09

Re: The lights are on...
 
Quote:

Originally Posted by martyh (Post 35631624)
The way things move in this country it'll still be 20-30yrs before we see anything

Indeed every green looney in the country will turn up at any site they think might be involved and make camp.

martyh 13-10-2013 18:22

Re: The lights are on...
 
Quote:

Originally Posted by Sirius (Post 35631637)
Indeed every green looney in the country will turn up at any site they think might be involved and make camp.

I want to see lorryloads of heavy plant and 10 miles of security fencing around a big hole in the ground as soon as any investment is announced

Sirius 13-10-2013 18:39

Re: The lights are on...
 
Quote:

Originally Posted by martyh (Post 35631645)
I want to see lorryloads of heavy plant and 10 miles of security fencing around a big hole in the ground as soon as any investment is announced

One mile exclusion zone with the military doing the guarding is what i would class as the minimum for a nuclear power station.

I did the guarding on Salisbury plain once when i was based in Tidworth. We were there stopping the CND idiots trying to get in the cruse missile sites when they deployed on the plain to train.

Boy was it fun and i must admit i did fell sorry for them because we had just returned from a tour in Londonderry where we had a bit of a hard time. So they got the brunt of it ;)

Hugh 13-10-2013 20:02

Re: The lights are on...
 
Quote:

Originally Posted by Sirius (Post 35631658)
One mile exclusion zone with the military doing the guarding is what i would class as the minimum for a nuclear power station.

I did the guarding on Salisbury plain once when i was based in Tidworth. We were there stopping the CND idiots trying to get in the cruse missile sites when they deployed on the plain to train.

Boy was it fun and i must admit i did fell sorry for them because we had just returned from a tour in Londonderry where we had a bit of a hard time. So they got the brunt of it ;)

Funny thing was, I never saw any reports of CND protests in the Warsaw Pact countries, or setting up of 'Peace Camps' around Soviet SS-20 bases....:dozey:

RizzyKing 13-10-2013 20:06

Re: The lights are on...
 
Until such time as a viable energy project can be completed and deliver benefits within a five year timeframe none of our spineless politicians will do a thing. They don't care about the majority of the country because they are not part of the majority and don't need to either worry or deal with the same stuff most of us do. As soon as something comes along that can be done quick so they can both announce it's start and successful and beneficial outcome in a single parliament's time they will keep doing what they have been doing for the last thirty years lots of talking and not much else.

Hugh 13-10-2013 20:16

Re: The lights are on...
 
I think they may be affected by power outages, just like the rest of us....

Pierre 13-10-2013 20:36

Re: The lights are on...
 
Quote:

Originally Posted by Hugh (Post 35631696)
Funny thing was, I never saw any reports of CND protests in the Warsaw Pact countries, or setting up of 'Peace Camps' around Soviet SS-20 bases....:dozey:

Not sure what your point is there?

Hugh 13-10-2013 20:45

Re: The lights are on...
 
Quote:

Originally Posted by Pierre (Post 35631718)
Not sure what your point is there?

We had to police protests and guard our bases from protestors, who thought what we were doing was evil - the same protestors didn't duplicate those behaviours in the countries of the 'other side', who also had nuclear weapons...

Pierre 13-10-2013 20:58

Re: The lights are on...
 
Quote:

Originally Posted by Hugh (Post 35631724)
We had to police protests and guard our bases from protestors, who thought what we were doing was evil - the same protestors didn't duplicate those behaviours in the countries of the 'other side', who also had nuclear weapons...

I thought that was what you meant, but didn't want to comment as that it show a massive wedge of naivety on your part.

The countries behind the iron curtain were not what you would call " free" countries.

If the mothers of Moscow or Leningrad had started to congregate outside the nuclear bases of the CCCP they would have bee carted off to the gulag.

martyh 13-10-2013 21:00

Re: The lights are on...
 
Quote:

Originally Posted by Pierre (Post 35631731)
I thought that was what you meant, but didn't want to comment as that it show a massive wedge of naivety on your part.

The countries behind the iron curtain were not what you would call " free" countries.

If the mothers of Moscow or Leningrad had started to congregate outside the nuclear bases of the CCCP they would have bee carted off to the gulag.

mmm possibly a lesson to be learned ?? ;)

Hugh 13-10-2013 21:01

Re: The lights are on...
 
Quote:

Originally Posted by Pierre (Post 35631731)
I thought that was what you meant, but didn't want to comment as that it show a massive wedge of naivety on your part.

The countries behind the iron curtain were not what you would call " free" countries.

If the mothers of Moscow or Leningrad had started to congregate outside the nuclear bases of the CCCP they would have bee carted off to the gulag.

That was the point I was trying to make (as I was in the Armed Forces at the time, and was actively involved in analysing and reporting on the USSR/Warsaw Pact capabilities and governmental systems) - the irony of people protesting against our "evil system", but they never felt the need to travel to the Warsaw Pact countries to do the same....

Pierre 13-10-2013 21:04

Re: The lights are on...
 
Quote:

Originally Posted by Hugh (Post 35631733)
That was the point I was trying to make (as I was in the Armed Forces at the time, and was actively involved in analysing and reporting on the USSR/Warsaw Pact capabilities and governmental systems) - the irony of people protesting against our "evil system", but they never felt the need to travel to the Warsaw Pact countries to do the same....

Yeah but wouldn't that be like going to Iran and campaigning for Christmas or Easter?

Hugh 13-10-2013 21:20

Re: The lights are on...
 
Quote:

Originally Posted by Pierre (Post 35631735)
Yeah but wouldn't that be like going to Iran and campaigning for Christmas or Easter?

I didn't realise that people campaigned for Christmas and Easter in the UK.;)

No, it would be like protesting against Nuclear Weapons in two countries that had Nuclear Weapons......:D

I respected their right to protest, I just objected to their hypocrisy about Warsaw Pact nukes (usually the answer given was "they need them for defence against the Western aggressors").

Osem 14-10-2013 15:43

Re: The lights are on...
 
Did the protestors even maintain a presence outside the Russian embassy for example?


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